Ionic Liquid-Mediated Homogeneous Esterification of Cinnamic Anhydride to Xylans
نویسندگان
چکیده
A new functional biopolymer was synthesized through an ionic liquid-mediated homogeneous grafting of cinnamic anhydride to xylans. The ionic liquid used was 1-allyl-3-methylimidazolium chloride (AMIMCl) ionic liquid. Xylans with degrees of substitution (DS) between 0.11 and 0.57 were accessible in a completely homogeneous system by changing catalysts (NaOH, KOH and LiOH), time, reaction temperature, and cinnamic anhydride/xylan molar ratio. The chemical structure and the thermal stability of the derivatives were characterized by Fourier transform infrared spectroscopy (FT-IR), 13C-NMR spectroscopy, and thermogravimetry. The thermal stability of the derivatives was reduced compared with the original xylan. Possible applications of the cinnamic anhydride-acylated xylan derivatives include wet-end papermaking, organic-inorganic composite films, and hydrogels.
منابع مشابه
Esterification Mechanism of Bagasse Modified with Glutaric Anhydride in 1-Allyl-3-methylimidazolium Chloride
The esterification of bagasse with glutaric anhydride could increase surface adhesion compatibility and the surface of derived polymers has the potential of immobilizing peptides or proteins for biomedical application. Due to its complicated components, the esterification mechanism of bagasse esterified with glutaric anhydride in ionic liquids has not been studied. In this paper, the homogenous...
متن کاملLi(OHCH2CH2NH2)(CF3OAC): A novel and homogeneous acidic ionic liquid catalyst for efficient synthesis of 2-amino-4H-chromene derivatives
The ionic liquid Li(OHCH2CH2NH2)(CF3OAC) was found to efficiently catalyze the three-component reaction between different enols, aldehydes, and malononitrile , leading to rapid synthesis of 2-amino-4H-chromene derivatives in fairly high yields. The catalyst is easily prepared, highly stable, simple to handle and recycled for several times without significant loss of activity. The method is simp...
متن کاملLi(OHCH2CH2NH2)(CF3OAC): A novel and homogeneous acidic ionic liquid catalyst for efficient synthesis of 2-amino-4H-chromene derivatives
The ionic liquid Li(OHCH2CH2NH2)(CF3OAC) was found to efficiently catalyze the three-component reaction between different enols, aldehydes, and malononitrile , leading to rapid synthesis of 2-amino-4H-chromene derivatives in fairly high yields. The catalyst is easily prepared, highly stable, simple to handle and recycled for several times without significant loss of activity. The method is simp...
متن کاملImidazolium Chloride Immobilized Fly Ash as a Heterogenized Organocatalyst for Esterification Reaction under Microwave Irradiation Heating
An efficient solventless one-pot procedure for the synthesis of imidazolium-based ionic liquid under microwave irradiation is described in which 1-methylimidazole was modified by organosilane (3-chloropropyl triethoxysilane). This ionic liquid 1-methyl-3-[(triethoxysilyl)propyl]imidazolium chloride (TMICl) is immobilized on Mechanically activated Fly Ash (MFA) by co-condensation method to d...
متن کاملHomogeneous synthesis and characterization of starch acetates in ionic liquid without catalysts
Homogeneous modification of corn starch with acetic anhydride was performed in ionic liquids 1-butyl-3-methylimidazolium chloride (BMIMCl) without catalysts. The results indicated that the pretreatment of starch, which starch was dissolved in BMIMCl at 1058C for 2 h before reaction, provided feasible reaction environment for starch functionalization. Optimum modification conditions for maximum ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 18 شماره
صفحات -
تاریخ انتشار 2017